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6.3 - Triazines, tetrazines, and fused ring polyaza systems

Abstract : The chemistry of triazines and tetrazines in 2019 was important in terms of chemistry (synthesis and functionalization) and in terms of applications. s-Triazine is the most studied heterocycle for biological applications and for materials applications, thanks to its C-3 symmetry and its electron-poor character (as organic frameworks and fluorescent materials). Many papers are reported with 1,2,4,5-tetrazines mainly for their use in bioorthogonal chemistry. as-Triazine chemistry deals with a few original syntheses and as usual with inverse electron Diels–Alder reactions. Finally, a few papers on purines, and pteridines are also reported.
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Marie-Aude Hiebel, Franck Suzenet. 6.3 - Triazines, tetrazines, and fused ring polyaza systems. Gordon W. Gribble; John A. Joule. Progress in Heterocyclic Chemistry, 32, Elsevier, pp.467-499, 2021, ⟨10.1016/B978-0-323-89812-6.00014-6⟩. ⟨hal-03652328⟩



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